Lead isotopes in snow and ice as an indicator of past changes to the Antarctic environmentEntry ID: ASAC_966
Abstract: From the abstracts of the referenced papers:
Techniques for Pb measurements have reached the stage where Antarctic ice with sub-picogram per gram concentrations can be reliably analysed for isotopic composition. Here, particular attention has been given to measuring the quantity of Pb added during the decontamination and sample storage stages of the sample preparation process because of their ... impact on accuracy at low concentrations. These stages, including the use of a stainless steel chisel for the decontamination, contributed ~5.2pg to the total sample analysed, amounting to a concentration increase of ~13fg per gram, which is significantly less than expected. Consequently the corrections to the isotopic ratios and concentration were also smaller. Other contributions to the blank, such as Pb fallout onto critical working areas in the HEPA-filtered laboratories, were also relatively small as was the amount of Pb leached from preconditioned perfluoroalkoxy (PFA) beakers during sample processing. The ion source contributed typically 89 plus or minus 19 fg to the blank. Although this was relatively large, its influence depended upon the amount of Pb available for analysis and it had the greatest impact when small volumes of samples with a very low concentration were analysed. A 15 months investigation of the leaching characteristics of Pb from a low-density polyethylene (LDPE) sample storage bottle showed 11 fg per cm per cm per day was released immediately following the initial 2 months cleaning process, but this decreased to immeasurable values after a further 3 months of cleaning.
Lead isotopic compositions and Pb and Ba concentrations have been measured in ice cores from Law Dome, East Antarctica, covering the past 6500 years. 'Natural' background concentrations of Pb (~0.4 pg/g) and Ba (~1.3 pg/g) are observed until 1884 AD, after which increased Pb concentrations and lowered 206Pb/207Pb ratios indicate the influence of anthropogenic Pb. The isotopic composition of 'natural' Pb varies within the range 206Pb/207Pb=1.20-1.25 and 208Pb/207Pb=2.46-2.50, with an average rock and soil dust Pb contribution of 8-12%. A major pollution event is observed at Law Dome between 1884 and 1908 AD, elevating the Pb concentration four-fold and changing 206Pb/207Pb ratios in the ice to ~1.12. Based on Pb isotopic systematics and Pb emission statistics, this is attributed to Pb mined at Broken Hill and smelted at Broken Hill and Port Pirie, Australia. Anthropogenic Pb inputs are at their greatest from ~1900 to ~1910 and from ~1960 to ~1980. During the 20th Century, Ba concentrations are consistently higher than 'natural' levels and are attributed to increased dust production, suggesting the influence of climate change and/or changes in land coverage with vegetation.
The fields in this dataset are:
Data Set Citation
Dataset Originator/Creator: Rosman, K.
Dataset Title: Lead isotopes in snow and ice as an indicator of past changes to the Antarctic environment
Dataset Series Name: CAASM Metadata
Dataset Release Date: 2004-06-22
Dataset Publisher: Australian Antarctic Data Centre
Dataset DOI: doi:10.4225/15/5874704e9487aOnline Resource: https://data.aad.gov.au/aadc/metadata/metadata_redirect.cfm?md=/AMD...
Start Date: 1996-09-30Stop Date: 1998-03-31
Paleo Temporal Coverage
Paleo Start Date: 7500 YBP
Paleo Stop Date: 0 YBP
Quality Values provided in temporal coverage are approximate only.
Access Constraints The data are publicly available for download from the provided URL.
PDF copies of the referenced papers are available for download to AAD staff only.
Use Constraints This data set conforms to the PICCCBY Attribution License
Please follow instructions listed in the citation reference provided at http://data.aad.gov.au/aadc/metadata/citation.cfm?entry_id=ASAC_966 when using these data.
Data Set Progress
Distribution Media: HTTP
Distribution Size: 157 kb
Distribution Format: Excel, Word
Distribution Media: HTTP
Distribution Size: 5.7 MB
Distribution Format: PDF
Vallelonga, P., Van de Velde, K., Candelone, J.P., Ly, C., Rosman, K.J.R., Boutron, C.F., Morgan, V.I., and Mackey, D.J. (2002), Recent advances in measurement of Pb isotopes in polar ice and snow at sub-picogram per gram concentrations using thermal ionisation mass spectrometry., Analytica Chimica Acta, 453, 1-12
Vallelonga, P., Van de Velde, K., Candelone, J.P., Morgan, V.I., Boutron, C.F. and Rosman, K.J.R. (2002), The lead pollution history of Law Dome, Antarctica, from isotopic measurements on ice cores: 1500 AD to 1989 AD., Earth Planet. Sci. Lett, 204, 291-306
Extended Metadata Properties
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Creation and Review Dates
DIF Creation Date: 2000-08-08
Last DIF Revision Date: 2017-01-27